So I moved my WordPress install to my domain root and the WordPress specific htaccess instructions have borked my WebDAV. Fortunately a little googling and I’ve got a solution.
Since running a multisite install, my htaccess rewrites a lot. Turning off the RewriteEngine inside he WebDAV direcetory solves this issue.
<br /> <IfModule mod_rewrite.c><br /> RewriteEngine Off<br /> </IfModule><br />